Oxidative deprotection of trimethylsilyl and tetrahydropyranyl ethers, acetals and ketals with N,N�?�?�?�?�?�?�?�?-dibenzyl-1,4-diazoniabicyclo
[2.2.2] octane peroxodisulfate under non-aqueous conditions

Mohammad Alikarami; Zahra Abbasi

Organic Chemistry: An Indian Journal
ISSN (PRINT): 0974-7516

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Abstract

Oxidative deprotection of trimethylsilyl and tetrahydropyranyl ethers, acetals and ketals with N,N�?�?�?�?�?�?�?�?-dibenzyl-1,4-diazoniabicyclo [2.2.2] octane peroxodisulfate under non-aqueous conditions

Author(s): Mohammad Alikarami, Zahra Abbasi

An efficient and convenient conversion of trimethylsilyl (TMS) and tetrahydropyranyl (THP) ethers, acetals and ketals to the corresponding carbonyl compoundswith N,NÂÃ‚Â’-dibenzyl-1,4-diazoniabicyclo [2.2.2] octane peroxodisulfate (DBDABCOPDS) under non-aqueous conditions is described.